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1 2 And 1 4 Addition Practice Problems
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In general to predict the products of an electrophilic addition to a diene you need to identify whether the diene is symmetrical or unsymmetrical If it is symmetrical you only need to protonate one of the double bonds since both double bonds result in the same products Practice Problems. Write out the products of 1,2 addition and 1,4- addition of a) HBr and Br. b) DBr to 1,3-cyclo-hexadiene. What is unusual about the products of 1,2- and 1,4- addition of HX to unsubstituted cyclic 1,3-dienes? Is the 1,2-addition product formed more rapidly at higher temperatures, even though it is the 1,4-addition product ...
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1 2 And 1 4 Addition Practice ProblemsQuestion #1. Cyclopentadiene Question #2 (2,5 dimethyl hexa-2-4-diene) Question #3: 1-Methyl Cyclohexadiene Conclusion Notes (Advanced) References and Further Reading 1. Recap: "1,2" vs. "1,4" Addition To Dienes, And "Kinetic Control" vs "Thermodynamic Control " The 1 2 addition has a smaller activation energy than 1 4 addition it occurs faster than 1 4 addition because the bromide nucleophile is closer to carbon 2 then to carbon 4 However the 1 4 product is more stable than the 1 2 product At low temperatures the products are formed irreversibly and reflect the relative rates of the two
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